form 12 - Mira.startflyjobs.co
form 12 - Mira.startflyjobs.co | dd form 137 7 pdf

Ten Simple (But Important) Things To Remember About Dd Form 12 12 Pdf | Dd Form 12 12 Pdf

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A sample of 20 g of dry Amberlyst A-21 was aboriginal able by suspending it in 100 mL booze for 30 min. After this, the admixture was filtered and done in booze for a added three times. This adjustment was again in dichloromethane. The adhesive was again broiled on a rotary evaporator at 50 °C until it was free-flowing and after larboard brief in a desiccator beneath vacuum. The dry weight of Amberlyst A-21 was 9.63 g. Amberlyst-21 (5 g) were again added to a band-aid of 2.86 g (15 mmol) copper(I) iodide in 75 mL acetonitrile and larboard to activity for 24 h at allowance temperature. The bread-and-er was again evaporated and the blooming adhesive was done with two 75 mL aliquots of acetonitrile, followed by two 75 mL aliquots of dichloromethane. The adhesive was again broiled on a rotary evaporator at 40 °C and after larboard brief in a desiccator beneath vacuum. The loading of nut per gram of adhesive was affected by celebratory the weight increases of the broiled sample of CuI on Amberlyst A-21. A weight access of 2.05 g (10.8 mmol CuI) was observed, which gave a polymer loading of 1.52 mmol CuI g−1.

form 12 - Mira.startflyjobs
form 12 – Mira.startflyjobs | dd form 137 7 pdf

6 N-(2-nitro-1-phenylethyl)aniline (Choudhary & Peddinti, 2011). Brown solid. m.p. 73-75 °C. IR (neat KBr, cm−1): ν = 3354, 3078, 3058, 3027, 2970, 2916, 2894, 1604, 1546, 1514, 1508, 1489, 1458, 1425, 1381, 1314, 1264, 1213, 1181, 1127, 1083, 1067, 1032, 994, 940, 879, 851, 822, 756, 727, 701, 654, 628, 533, 511. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.35 (d, 1H, Ha, J = 6.4 Hz), 4.70 (d, 2H, Hb, J = 6.8 Hz), 5.15 (q, 1H, Hc, J = 6.8 Hz), 6.60 (d, 2H, Hd, Jo = 8.6 Hz, Jm = 1  Hz), 6.75 (t, 1H, He, J = 7.4 Hz), 7.15 (t, 2H, Hf, J = 8.0  Hz), 7.30 (m,1H Hg), 7.40 (m, 4H Hh, Hi). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.7, 80.0, 113.9, 119.0, 126.5, 128.7, 129.3, 129.4, 137.8, 145.7. MS (ES ) m∕z = 242.07 [MH ], 122.03, 94.06, 92.04, 86.98, 92.04.

7a N-(2-nitro-1-(p-tolyl)ethyl)aniline (Yang, Xia & Huang, 2011). Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3400, 3091, 3053, 3027, 2954, 2921, 2863, 1633, 1603, 1554, 1506, 1458, 1436, 1423, 1378,1338, 1316, 1266, 1214, 1182, 1157, 1113, 1068, 1031, 1021, 994, 971, 914, 872, 814, 752, 693, 669, 510. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.33 (s, 3H, Ha), 4.35 (d, 1H, Hb, J = 6.1 Hz), 4.70 (m, 2H, Hc), 5.15 (q, 1H, Hd, J = 6.7 Hz), 6.61 (d, 2H, He, J = 8.6  Hz), 6.75 (t, 1H, Hf, J = 7.4 Hz), 7.14 (t, 2H, Hg, Jo = 8.0 Hz, Jm = 1.2 Hz), 7.18 (d, 2H, Hh, J = 7.9 Hz), 7.25 (d, 2H, Hi, J = 8.2 Hz).13C NMR (CDCl3, 126 MHz) δ (ppm): 21.1, 56.5, 80.0, 113.9, 118.9, 126.4, 129.4, 130.0, 134.7, 138.5, 145.8. MS (ES ) m∕z = 257.10 [MH ], 196.12, 164.05, 118.06, 94.06, 91.07.

7c N-(1-(4-bromophenyl)-2-nitroethyl)aniline. Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3404, 3087, 3053, 3026, 2963, 2918, 1603, 1553, 1508, 1423, 1404, 1377, 1335, 1314, 1263, 1215, 1180, 1155, 1128, 1099, 1072, 1011, 993, 902, 918, 876, 822, 752, 692, 648, 540, 509. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.40 (d, 1H, Ha, J = 6.3 Hz), 4.69 (d, 2H, Hb, J = 6.6 Hz), 5.12 (q, 1H, Hc, J = 6.6 Hz), 6.58 (d, 2H, Hd, J = 7.7 Hz), 6.75 (t, 1H, He, J = 7.4 Hz), 7.15 (t, 2H, Hf J = 7.4 Hz), 7.28 (d, 2H, Hg, J = 8.5 Hz), 7.51 (d, 2H, Hh, J = 8.5 Hz ). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.1, 79.7, 113.9, 119.2, 122.6, 128.2, 129.4, 132.5, 137.8, 145.3. MS (ES ) m∕z = 323.04 [MH ], 262.04, 183.99, 103.02, 93.98, 77.01.

7d N-(2-nitro-1-(2-nitrophenyl)ethyl)aniline (Tajbakhsh, Farhang & Hosseini, 2014). Yellow-brown solid. m.p. 77-79 °C. IR (neat, KBr, cm−1): ν = 3375, 3104, 3078, 3030, 2920, 2862, 1622, 1580, 1560, 1522, 1474, 1435, 1386, 1340, 1289, 1263, 1250, 1215, 1182, 1154, 1131, 1086, 1066, 937, 921, 879, 860, 851, 811, 792, 750, 724, 708, 673, 647, 627, 560, 517, 505. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.83 (m, 2H, Ha), 5.01 (dd, 1H, Hb J = 3.7 Hz, 12.4 Hz), 5.80 (m, 1H, Hc), 6.48 (d, 2H, Hd, Jo = 8.6 Hz, Jm = 1.0 Hz), 6.75 (t, 1H, He, Jo = 7.4 Hz, Jm = 1.0 Hz), 7.10 (t, 2H, Hf, J = 8.0 Hz), 7.50 (t, 1H, Hg, Jo = 8.1 Hz, Jm = 1.4 Hz), 7.60 (t, 1H, Hh, Jo = 7.5 Hz, Jm = 1.2  Hz), 7.69 (d, 1H, Hi, Jo = 7.9 Hz, Jm = 1.3 Hz), 8.09 (d, 1H, Hj, Jo = 8.2 Hz, Jm = 1.2 Hz).

7e 3-(2-Nitro-1-(phenylamino)ethyl)phenol. Dark-red oil. IR (neat NaCl, cm−1): ν = 3407, 3097, 3072, 3036, 2923, 2856, 1613, 1580, 1560, 1509, 1451, 1422, 1380, 1344, 1325, 1289, 1273, 1257, 1215, 1186, 1154, 1138, 1083, 1066, 1028, 996, 970, 934, 918, 876, 860, 844, 792, 750, 718, 692, 669, 643, 611, 518. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.38 (m, 1H, Ha), 4.69 (d, 2H, Hb, J = 6.7 Hz), 5.01 (broad, 1H, Hc), 5.11 (q, 1H, Hd, J = 6.1  Hz), 6.60 (d, 2H, He, J = 8.6 Hz), 6.75 (t, 1H, Hf, J = 7.4  Hz), 6.76 (m, 1H, Hg), 6.85 (s, 1H, Hh), 6.95 (d, 1H, Hi, J = 7.6 Hz), 7.15 (t, 2H, Hj, Jo = 7.0 Hz, Jm = 1.2 Hz), 7.25 (t, 1H, Hk, J = 7.9 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.4, 79.9, 113.4, 113.9, 115.7, 118.6, 119.0, 129.4, 130.6, 139.6, 145.6, 156.4. MS (ES ) m∕z = 259.10 [MH ], 212.17, 198.06, 166.06, 120.07, 94.05.

dd form 12 - Mira.startflyjobs
dd form 12 – Mira.startflyjobs | dd form 137 7 pdf

7g N-(1-([1,1-biphenyl]-4-yl)-2-nitroethyl)aniline. Yellow-red solid. m.p. 97-99 °C. IR (neat, KBr, cm−1): ν = 3398, 3055, 3030, 2960, 2918, 1603, 1549, 1511, 1486, 1476, 1460, 1441, 1422, 1381, 1314, 1266, 1257, 1213, 1180, 1155, 1133, 1076, 1008, 993, 920, 876, 837, 768, 755, 732, 695, 650, 621, 561, 507. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.42 (d, 1H, Ha, J = 6.4 Hz), 4.75 (d, 2H, Hb, J = 6.8 Hz), 5.22 (q, 1H, Hc, J = 6.6 Hz), 6.65 (d, 2H, Hd, Jo = 8.6 Hz, Jm = 1.0 Hz), 6.75 (t, 1H, He, Jo = 7.4 Hz, Jm = 1.0  Hz), 7.16 (t, 2H, Hf, Jo = 8.0 Hz, Jm = 1.2 Hz), 7.35 (t, 1H, Hg, Jo = 7.4 Hz, Jm = 1.3 Hz), 7.43 (t, 2H, Hh, J = 7.6 Hz), 7.47 (d, 2H, Hi, Jo = 8.1 Hz, Jm = 1.6 Hz), 7.55 (d, 2H, Hj, Jo = 8.2 Hz, Jm = 2.0 Hz), 7.60 (d, 2H, Hk, Jo = 8.4 Hz, Jm = 2.0 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.5, 79.9, 114.0, 119.0, 126.9, 127.1, 127.6, 128.0, 128.9, 129.4, 136.7, 140.3, 141.7, 145.7. MS (ES ) m∕z = 327.03 [MH ], 80.91.

7h N-(1-(3,4-dichlorophenyl)-2-nitroethyl)aniline. Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3403, 3093, 3054, 3025, 2960, 2922, 2857, 1604, 1556, 1508, 1472, 1423, 1378, 1313, 1262, 1214, 1194, 1181, 1136, 1075, 1033, 997, 929, 884, 826, 752, 697, 668, 619, 584. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.43 (broad, 1H, Ha), 4.68 (d, 2H, Hb, J = 6.9 Hz), 5.11 (q, 1H, Hc, J = 6.0 Hz), 6.57 (d, 2H, Hd, Jo = 9.1 Hz, Jm = 0.95 Hz), 6.78 (t, 1H, He, Jo = 7.4 Hz, Jm = 1.0 Hz), 7.15 (t, 2H, Hf, J = 8.0 Hz), 7.25 (d, 1H, Hg, J = 9.3 Hz), 7.45 (d, 1H, Hh, J = 8.2 Hz), 7.51 (s, 1H, Hi). 13C NMR (CDCl3, 126 MHz) δ (ppm): 55.8, 79.6, 114.0, 119.5, 125.8, 128.6, 129.5, 131.6, 132.9, 133.6, 138.1, 145.1. MS (ES ) m∕z = 312.97 [MH ], 252.96, 252.02, 173.91, 101.73, 93.98.

7i N-(1-(2,6-dichlorophenyl)-2-nitroethyl)aniline. Red solid. m.p. 96–99 °C. IR (neat, KBr, cm−1): ν = 3388, 3061, 3049, 3033, 2982, 2928, 2855, 1603, 1581, 1555, 1508, 1495, 1457, 1441, 1381, 1339, 1311, 1289, 1266, 1250, 1216, 1200, 1181, 1152, 1123, 1089, 1056, 1028, 993, 923, 901, 885, 860, 834, 793, 774, 758, 726, 695, 640, 621, 558, 495. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.73 (dd, 1H, Ha, J = 5.2 Hz, 12.3 Hz), 4.95 (d, 1H, Hb, 11.2 Hz), 5.07 (dd, 1H, Hc, 9.9 Hz, 12.3 Hz), 6.29 (ddd, 1H, Hd, 11.2 Hz, 10.0 Hz, 5.3 Hz), 6.74 (m, 3H, He, Hf), 7.13-7.19 (m, 3H, Hg, Hh), 7.27-7.38 (m, 2H, Hi). 13C NMR (CDCl3, 126 MHz) δ (ppm): 53.3, 76.5, 114.2, 119.4, 129.4, 130.2, 132.2, 145.3. MS (ES ) m∕z = 310.97 [MH ], 250.02, 136.98, 124.95, 93.33.

7j N-(1-(benzo[d ][1,3]dioxol-5-yl)-2-nitroethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3393, 3051, 3028, 2960, 2896, 1607, 1559, 1508, 1491, 1449, 1378, 1339, 1313, 1246, 1184, 1155, 1110, 1036, 997, 971, 929, 871, 816, 755, 733, 693, 668, 639. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.35 (broad, 1H, Ha), 4.66 (d, 2H, Hb, J = 6.7 Hz), 5.07 (q, 1H, Hc, J = 6.0 Hz), 5.96 (m, 2H, Hd), 6.61 (d, 2H, He, Jo = 8.6  Hz, Jm = 1.0 Hz), 6.75 (t, 1H, Hf, J = 7.3 Hz), 6.79 (d, 1H, Hg, J = 8.6 Hz), 6.87 (m, 2H, Hh, Hi), 7.15 (t, 2H, Hj, Jo = 7.4 Hz, Jm = 2.0 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.5, 80.2, 101.4, 106.7, 108.9, 113.9, 119.0, 120.0, 129.4, 131.6, 145.6, 147.9, 148.5. MS (ES ) m∕z = 287.10 [MH ], 194.02, 148.03, 94.05, 91.64, 90.99.

7k N-(1-nitropentan-2-yl)aniline. Red oil. IR (neat NaCl, cm−1): ν = 3367, 3055, 3017, 2965, 2931, 2875, 1684, 1604, 1555, 1500, 1463, 1445, 1383, 1362, 1317, 1258, 1220, 1185, 1140, 1075, 1047, 994, 922, 839, 756, 692, 669. 1H NMR (CDCl3, 500 MHz) δ (ppm): 0.95 (t, 3H, Ha, J = 7.3 Hz), 1.40–1.70 (m, 4H, Hb, Hc), 3.65 (d, 1H, Hd, J = 7.2 Hz), 4.10 (m, 1H, He), 4.40 (dd, 1H, Hf, J = 6.2 Hz, 11.8 Hz), 4.50, (dd, 1H, Hg, J = 5.1 Hz, 11.8 Hz), 6.65 (d, 2H, Hh, Jo = 8.6 Hz, Jm = 0.9  Hz), 6.75 (t, 1H, Hi, Jo = 7.4 Hz, Jm = 0.9 Hz), 7.20 (t, 2H, Hj, Jo = 8.0 Hz, Jm = 1.2 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 13.8, 19.1, 35.1, 52.0, 78.1, 113.5, 118.7, 129.6, 146.0. MS (ES ) m∕z = 209.10 [MH ], 148.11, 118.25, 106.02, 93.08, 40.98.

da form 12 - Mira.startflyjobs
da form 12 – Mira.startflyjobs | dd form 137 7 pdf

7l N-(1-cyclohexyl-2-nitroethyl)aniline. Red oil. (neat NaCl, cm−1): ν = 3399, 3053, 3022, 2930, 2853, 1601, 1557, 1504, 1449, 1427, 1381, 1348, 1315, 1256, 1215, 1180, 1155, 1123, 1072, 1030, 993, 964, 914, 893, 874, 841, 752, 692, 667, 619, 509. 1H NMR (CDCl3, 500 MHz) δ: 1.00–1.30 (m, 5H, Ha, Hb, Hc), 1.55-1.85 (m, 5H, Hd, He, Hf), 1.91 (d, 1H, Hg, J = 12.5 Hz), 3.70 (d, 1H, Hh, J = 9.8 Hz), 3.94–4.00 (m, 1H, Hi), 4.45 (dd, 1H, Hj J = 6.3 Hz, 12.1 Hz), 4.55 (dd, 1H, Hk, J = 5.7 Hz, 12.1 Hz), 6.65 (d, 2H, Hl, J = 7.7 Hz), 6.75 (t, 1H, Hm, J = 7.3 Hz), 7.2 (t, 2H, Hn, Jo = 7.9 Hz, Jm = 1.0 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 26.0, 26.1, 28.3, 29.6, 40.6, 57.0, 76.5, 113.5, 118.4, 129.5, 146.6. MS (ES ) m∕z = 249.14 [MH ], 188.17, 109.08, 106.02, 94.71, 67.06.

7m Ethyl 3-nitro-2-(phenylamino)propanoate. Red oil. IR (neat NaCl, cm−1): ν = 3388, 3054, 3028, 2983, 2936, 2905, 2870, 1742, 1605, 1558, 1507, 1447, 1421, 1380, 1313, 1281, 1256, 1215, 1158, 1100, 1078, 1053, 1018, 958, 922, 875, 856, 757, 693. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.29 (t, 3H, Ha, J = 7.1 Hz), 4.29 (m, 2H, Hb), 4.51 (d, 1H, Hc, J = 7.7 Hz), 4.64 (m, 1H, Hd), 4.79 (dd, 1H, He, J = 5.0 Hz, 13.7 Hz), 4.87 (dd, 1H, Hf, J = 4.5 Hz, 13.7 Hz), 6.68 (d, 2H, Hg, J = 7.7 Hz), 6.84 (t, 1H, Hh, J = 7.4 Hz), 7.22 (t, 2H, Hi, Jo = 8.0 Hz, Jm = 1.9 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 14.0, 54.9, 62.7, 75.6, 113.8, 119.7, 129.6, 145.2, 169.5. MS (ES ) m∕z = 239.10 [MH ], 178.11, 150.07, 104.02, 93.02, 77.02.

8c 3-Methyl-N-(2-nitro-1-phenylethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3396, 3027, 2949, 2919, 2859, 1608, 1591, 1558, 1508, 1491, 1453, 1424, 1380, 1339, 1323, 1269, 1215, 1178, 1126, 1078, 1032, 998, 970, 926, 847, 768, 699, 668, 624, 592, 527. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.24 (s, 3H, Ha), 4.31 (d, 1H, Hb, J = 6.4 Hz), 4.71 (d, 2H, Hc, J = 6.8 Hz), 5.17 (q, 1H, Hd, J = 6.7 Hz), 6.41 (d, 1H, He, Jo = 8.0 Hz, Jm = 2.2 Hz), 6.46 (s, 1H, Hf), 6.58 (d, 1H, Hg, J = 7.5 Hz), 7.03 (t, 1H, Hh, J = 7.8 Hz), 7.31–7.34 (m, 1H, Hi), 7.35–7.41 (m, 4H, Hj, Hk). 13C NMR (CDCl3, 126 MHz) δ (ppm): 21.5, 56.6, 79.9, 110.9, 114.8, 119.9, 126.4, 128.6, 129.2, 129.3, 137.8, 139.2, 145.7. MS (ES ) m∕z = 257.08 [MH ], 196.11, 149.99, 107.98, 104.07, 78.05.

8d 2-Methyl-N-(2-nitro-1-phenylethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3417, 3058, 3024, 2967, 2915, 2853, 1636, 1608, 1588, 1554, 1508, 1481, 1455, 1423, 1377, 1345, 1313, 1263, 12161189, 1160, 1136, 1074, 1053, 1030, 1003, 987, 968, 923, 844, 751, 701, 653, 621, 592, 536. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.23 (s, 3H, Ha), 4.35 (d, 1H, Hb, J = 5.5 Hz), 4.75 (d, 2H, Hc, J = 6.7 Hz), 5.19 (q, 1H, Hd, J = 6.4 Hz), 6.46 (d, 1H, He, J = 8.0 Hz), 6.69 (t, 1H, Hf, Jo = 7.3 Hz, Jm = 0.8 Hz), 7.00 (t, 1H, Hg, Jo = 7.5 Hz, Jm = 1.0  Hz), 7.08 (d, 1H, Hh, J = 7.4 Hz), 7.31–7.34 (m, 1H, Hi), 7.36–7.42 (m, 4H, Hj, Hk). 13C NMR (CDCl3, 126 MHz) δ (ppm): 17.5, 56.8, 80.3, 111.2, 118.5, 123.0, 126.4, 127.1, 128.7, 129.4, 130.4, 137.9, 143.7. MS (ES ) m∕z = 257.08 [MH ], 196.11, 149.99, 107.98, 104.07, 77.99.

8e 4-Ethyl-N-(2-nitro-1-phenylethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3400, 3062, 3027, 2962, 2928, 2889, 2870, 1615, 1557, 1521, 1494, 1452, 1426, 1414, 1377, 1343, 1313, 1265, 1212, 1184, 1134, 1113, 1076, 1029, 1000, 968, 921, 826, 767, 700, 644, 628, 540. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.15 (t, 3H, Ha, J = 7.6 Hz), 2.50 (q, 2H, Hb, J = 7.6 Hz), 4.27 (broad, 1H, Hc), 4.70 (d, 2H, Hd, J = 6.8 Hz), 5.14 (broad, 1H, He), 6.55 (d, 2H, Hf, J = 8.5 Hz), 6.98 (d, 2H, Hg, J = 8.5 Hz), 7.32 (m, 1H, Hh), 7.36–7.41 (m, 4H, Hi, Hj). 13C NMR (CDCl3, 126 MHz) δ (ppm): 15.8, 27.9, 57.0, 80.0, 114.1, 126.5, 128.6, 128.7, 129.3, 134.8, 138.0, 143.6. MS (ES ) m∕z = 271.08 [MH ], 210.11, 121.37, 104.01, 103.69, 78.06.

Learn How to Fill the DD form 12 Record of Emergency Data - YouTube - dd form 137 7 pdf
Learn How to Fill the DD form 12 Record of Emergency Data – YouTube – dd form 137 7 pdf | dd form 137 7 pdf

8h 1-(4-((2-Nitro-1-phenylethyl)amino)phenyl)ethanone. Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3319, 3156, 3087, 3068, 3027, 2963, 2919, 2864, 1651, 1594, 1562, 1533, 1496, 1457, 1425, 1378, 1362, 1356, 1283, 1216, 1181, 1136, 1117, 1073, 1025, 955, 926, 834, 812, 765, 724, 704, 638, 599, 577. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.47 (s, 3H, Ha), 4.75 (m, 2H, Hb), 4.99 (d, 1H, Hc, J = 6.7 Hz), 5.26 (q, 1H, Hd, J = 7.3 Hz), 6.60 (d, 2H, He, Jo = 6.9  Hz, Jm = 1.9 Hz), 7.33-7.42 (m, 5H, Hf, Hg, Hh), 7.79 (d, 2H, Hi, Jo = 6.9 Hz, Jm = 1.9 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 26.1, 56.0, 79.8, 112.7, 126.4, 128.2, 129.0, 129.5, 130.7, 136.8, 149.8, 196.5. MS (ES ) m∕z = 285.10 [MH ], 224.14, 135.09, 104.07, 93.08, 42.99.

8i 4-((2-Nitro-1-phenylethyl)amino)benzonitrile. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3337, 3059, 3027, 3005, 2965, 2915, 2843, 2215, 1605, 1558, 1519, 1494, 1458, 1417, 1377, 1343, 1311, 1278, 1217, 1179, 1139, 1102, 1074, 1028, 1001, 968, 920, 825, 761, 700, 668, 627, 606, 546. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.71 (dd, 1H, Ha, J = 8.5 Hz, 12.5 Hz), 4.76 (dd, 1H, Hb, J = 4.7 Hz, 12.5 Hz), 5.03 (broad d, 1H, Hc, J = 6.5 Hz), 5.20 (m, 1H Hd), 6.60 (d, 2H, He, Jo = 8.9 Hz, Jm = 2.0 Hz), 7.34–7.38 (m, 3H, Hf, Hg), 7.38–7.42 (m, 4H, Hh, Hi). 13C NMR (CDCl3, 126 MHz) δ (ppm): 55.9, 79.7, 100.7, 113.5, 120.0, 126.3, 129.1, 129.6, 133.8, 136.9, 149.2. MS (ES ) m∕z = 268.10 [MH ], 221.12, 143.08, 118.10, 91.05.

8j 3-Nitro-N-(2-nitro-1-phenylethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3392, 3085, 3066, 3030, 3004, 2971, 2921, 2862, 1623, 1561, 1526, 1507, 1459, 1424, 1379, 1348, 1276, 1220, 1129, 1099, 1081, 998, 964, 890, 853, 817, 793, 761, 737, 700, 670, 624, 529. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.70-4.75 (dd, 1H, Ha, J = 8.7 Hz, 12.4 Hz), 4.75–4.80 (dd, 1H, Hb, J = 4.5 Hz, 12.4  Hz), 4.88 (d, 1H, Hc, J = 6.7 Hz), 5.23 (d, 1H, Hd, J = 4.7, 6.6, 8.5 Hz), 6.89 (d, 1H, He, Jo = 8.2 Hz, Jm = 2.0 Hz), 7.25 (t, 1H, Hf, J = 8.2 Hz), 7.34–7.36 (m, 1H, Hg), 7.38–7.42 (m, 5H, Hh, Hi, Hj), 7.55 (d, 1H, Hk Jo = 8.2  Hz, Jm = 1.4 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.4, 79.9, 108.0, 113.5, 119.6, 126.3, 129.1, 129.6, 130.0, 136.4, 146.6, 149.3. MS (ES ) m∕z = 288.08 [MH ], 150.05, 138.99, 104.06, 91.97, 77.99.

8k 2,5-Dichloro-N-(2-nitro-1-phenylethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3483, 3396, 3090, 3067, 3031, 2963, 2921, 2853, 1594, 1559, 1508, 1485, 1459, 1417, 1378, 1343, 1294, 1211, 1136, 1094, 1046, 952, 910, 835, 794, 768, 700, 613, 581, 532. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.75 (m, 2H, Ha), 5.18 (q, 1H, Hb, J = 6.4 Hz), 5.23 (d, 1H, Hc, J = 6.9 Hz), 6.51 (s, 1H, Hd, Jm = 2.3 Hz), 6.65 (d, 1H, He, Jo = 8.4 Hz, Jm =2.3 Hz), 7.18 (d, 1H, Hf, J = 8.4 Hz), 7.35-7.42 (m, 5H, Hg, Hh, Hi). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.3, 79.9, 112.4, 118.2, 118.7, 126.3, 129.1, 129.6, 130.0, 133.6, 136.4, 142.5. MS (ES ) m∕z = 312.97 [MH ], 252.02, 217.96, 173.91, 101.73, 93.98.

8l (E)-N-(2-nitro-1-phenylethyl)-4-(phenyldiazenyl)aniline. Red solid. m.p. 103–105 °C. IR (neat, KBr, cm−1): ν = 3483, 3396, 3090, 3067, 3031, 2963, 2921, 2853, 1594, 1559, 1508, 1485, 1459, 1417, 1378, 1343, 1294, 1211, 1136, 1094, 1046, 952, 910, 835, 794, 768, 700, 613, 581, 532. 1H NMR (CDCl3, 500 MHz) δ (ppm): 4.77 (m, 1H, Ha), 4.88 (broad, 1H, Hb), 5.28 (broad, 1H, Hc), 6.69 (d, 2H, Hd, Jo = 6.8 Hz, Jm = 2.1 Hz), 7.32–7.42 (m, 6H, He, Hf, Hg, Hh), 7.46 (t, 2H, Hi, Jo = 7.5 Hz, Jm = 1.5 Hz), 7.79 (d, 2H, Hj, Jo = 6.9  Hz, Jm = 2.1 Hz), 7.82 (d, 2H, Hk, J = 8.4 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 56.3, 79.8, 113.6, 122.4, 125.1, 126.4, 128.9, 129.0, 129.5, 130.0, 137.0, 145.8, 148.2, 152.9. MS (ES ) m∕z = 347.16 [MH ], 197.07, 104.13, 91.97, 77.07, 65.04.

da form 12 - Mira.startflyjobs
da form 12 – Mira.startflyjobs | dd form 137 7 pdf

4a 3-Nitro-N-(2-nitro-1-(p-tolyl)ethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3398, 3089, 3027, 2923, 2864, 1624, 1588, 1559, 1536, 1422, 1380, 1351, 1266, 1214, 1181, 1109, 1096, 1071, 1044, 1025, 996, 966, 918, 859, 820, 794, 758, 739, 673, 521. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.34 (s, 3a, Ha), 4.72 (m, 2H, Hb), 4.86 (d, 1H, Hc, J = 6.7 Hz), 5.19 (ddd, 1H, Hd, J = 8.4 Hz, 7.0 Hz, 4.7 Hz), 6.89 (d, 1H, He, Jo = 8.2  Hz, Jm = 0.7 Hz), 7.2 (d, 2H, Hf, J = 8.9 Hz), 7.24-7.29 (m, 3H, Hg, Hh), 7.41 (s, 1H, Hi, Jm = 2.3 Hz), 7.56 (d, 1H, Hj, Jo = 8.1 Hz, Jm = 0.8 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 21.1, 56.2, 80.0, 108.0, 113.4, 119.6, 126.2, 130.0, 130.2, 133.4, 139.0, 146.7, 149.3. MS (ES ) m∕z = 302.10 [MH ], 164.08, 118.10, 121.03, 117.71, 91.05.

4b 4-Chloro-N-(1-(4-methoxyphenyl)-2-nitroethyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3390, 3106, 3070, 3034, 3008, 2962, 2936, 2916, 2838, 1605, 1559, 1513, 1497, 1464, 1421, 1379, 1340, 1310, 1254, 1176, 1121, 1091, 1032, 970, 826, 783, 731, 682, 640, 564, 548, 525, 509. 1H NMR (CDCl3, 500 MHz) δ (ppm): 3.79 (s, 3H, Ha), 4.4 (d, 1H, Hb, J = 6.4 Hz), 4.67 (d, 2H, Hc, J = 6.7  Hz), 5.06 (q, 1H, Hd, J = 6.7 Hz), 6.52 (d, 2H, He, J = 8.9  Hz), 6.90 (d, 2H, Hf, J = 8.8 Hz), 7.08 (d, 2H, Hg, J = 8.9  Hz), 7.28 (d, 2H, Hh, J = 8.6 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 55.3, 56.3, 80.1, 114.8, 115.1, 127.6, 129.2, 131.2, 139.1, 144.3, 159.9. MS (ES ) m∕z = 307.09 [MH ], 180.05, 119.04, 91.06.

4c 3-(1-((4-methoxyphenyl)amino)-2-nitroethyl)phenol. Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3361, 3306, 3066, 3035, 3000, 2952, 2931, 2827, 1591, 1560, 1513, 1457, 1377, 1298, 1239, 1183, 1127, 1035, 997, 934, 827, 788, 730, 699, 517. 1H NMR (CDCl3, 500 MHz) δ (ppm): 3.71 (s, 3H, Ha), 4.66 (d, 2H, Hb, J = 6.7 Hz), 4.74 (m, 1H, Hc), 5.02 (t, 1H, Hd, J = 6.7 Hz), 5.16-5.38 (broad, 1H, He), 6.57 (d, 2H, Hf, Jo = 8.9 Hz, Jm = 2.3 Hz), 6.73 (d, 2H, Hg, Jo = 8.9 Hz, Jm = 2.2 Hz), 6.77 (d, 1H, Hh, Jo = 9.9 Hz, Jm = 0.6 Hz), 6.85 (s, 1H, Hi, Jm = 2.0 Hz), 6.94 (d, 1H, Hj, J = 8.6 Hz, Jm = 1.5 Hz), 7.24 (t, 1H, Hk, J = 7.9 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 55.7, 57.5, 80.0, 114.6, 115.0, 115.7, 117.2, 122.4, 130.2, 130.6, 139.7, 139.8, 144.0, 153.0, 156.5. MS (ES ) m∕z = 289.07 [MH ], 200.15, 166.06, 123.92.

4d 4-bromo-N-(1-cyclohexyl-2-nitroethyl)aniline. Red solid. IR m.p. 74–75 °C. IR (neat, KBr, cm−1): ν = 3405, 3386, 3100, 3077, 3064, 3038, 2929, 2851, 1598, 1558, 1509, 1489, 1446, 1424, 1387, 1354, 1318, 1299, 1250, 1217, 1184, 1155, 1135, 1115, 1096, 1079, 1030, 1014, 1000, 971, 931, 915, 892, 816, 803, 745, 699, 672, 639, 597, 508, 442, 423. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.00-1.30 (m, 5H, Ha, Hb, Hc), 1.60 (m, 1H, Hd), 1.65-1.85 (m, He, Hf), 1.90 (m, Hg), 3.72 (d, 1H, Hh, J = 9.8  Hz), 3.92 (m, 1H, Hi), 4.46, (dd, 1H, Hj, J = 6.8 Hz, 12.2 Hz), 4.53 (dd, 1H, Hk, J = 5.2 Hz, 12.2 Hz), 6.53 (d, 2H, Hl, J = 7.4 Hz), 7.26 (m, 2H, Hm). 13C NMR (CDCl3, 126 MHz) δ (ppm): 25.9, 26.1, 28.9, 29.6, 40.8, 57.2, 76.6, 110.0, 115.0, 132.3, 145.7. MS (ES ) m∕z = 325.03 [MH ], 169.93, 154.07, 136.05, 78.89, 60.02.

4e 4-methyl-N-(2-nitro-1-(2-nitrophenyl)ethyl)aniline. Yellow-red solid. m.p. 85-87 °C. IR (neat, KBr, cm−1): ν = 3375, 3104, 3078, 3030, 2920, 2862, 1622, 1580, 1560, 1522, 1474, 1435, 1386, 1340, 1289, 1263, 1250, 1215, 1182, 1154, 1131, 1086, 1066, 937, 921, 879, 860, 851, 811, 792, 750, 724, 708, 673, 647, 627, 560, 517, 505. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.18 (s, 3H, Ha), 4.64-4.86 (broad, 1H, Hb), 4.83 (dd, 1H, Hc, J = 7.6 Hz, 12.5 Hz), 5.00 (dd, 1H, Hd, J = 3.7 Hz, 12.5 Hz), 5.76 (dd, 1H, He, J = 3.7 Hz, 7.6 Hz), 6.40 (d, 2H, Hf, J = 8.5 Hz), 6.66 (d, 2H, Hg, J = 8.5 Hz), 7.49 (t, 1H, Hh, Jo = 7.8  Hz, Jm = 1.5 Hz), 7.60 (t, 1H, Hi, Jo = 7.6 Hz, Jm = 1.4 Hz), 7.68 (d, 1H, Hj, Jo = 7.8 Hz, Jm = 1.4 Hz), 8.08 (d, 1H, Hk, Jo = 8.1 Hz, Jm = 1.4 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 20.4, 52.9, 79.3, 113.8, 125.7, 128.7, 129.0, 129.6, 130.0, 133.5, 134.4, 142.5, 148.7. MS (ES ) m∕z = 302.10 [MH ], 241.15, 120.05, 119.73, 107.05.

form 12 - Mira.startflyjobs
form 12 – Mira.startflyjobs | dd form 137 7 pdf

4g N-(1-(4-bromophenyl)-2-nitroethyl)-4-ethylaniline. Red oil. IR (neat NaCl, cm−1): ν = 3377, 3086, 3015, 2957, 2919, 2860, 1604, 1582, 1547, 1511, 1478, 1446, 1414, 1369, 1330, 1307, 1259, 1211, 1178, 1126, 1107, 1097, 1069, 1039, 1007, 962, 917, 820, 759, 726, 661, 648, 532. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.15 (t, 3H, Ha, J = 7.6 Hz), 2.50 (q, 2H, Hb, J = 7.6 Hz), 4.29 (d, 1H, Hc, J = 6.1 Hz), 4.67 (d, 2H, Hd, J = 6.7 Hz), 5.09 (q, 1H, He, J = 6.5 Hz), 6.52 (d, 2H, Hf, Jo = 8.5 Hz, Jm = 2.0 Hz), 6.98 (d, 2H, Hg, J = 8.5 Hz), 7.28 (d, 2H, Hh, Jo = 8.4 Hz, Jm = 1.7 Hz), 7.50 (d, 2H, Hi, Jo = 8.5 Hz, Jm = 1.9 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 15.8, 27.9, 56.5, 79.8, 114.1, 122.6, 128.2, 128.8, 132.5, 135.2, 137.0, 143.2. MS (ES ) m∕z = 351.08 [MH ], 335.77, 180.26, 90.98, 64.97.

4h 4-methyl-N-(1-nitropentan-2-yl)aniline. Red oil. IR (neat NaCl, cm−1): ν = 3398, 3027, 2965, 2933, 2871, 1621, 1588, 1553, 1520, 1468, 1429, 1383, 1354, 1321, 1305, 1259, 1230, 1208, 1188, 1155, 1123, 1038, 993, 921, 813, 735, 644, 628, 511. 1H NMR (CDCl3, 500 MHz) δ (ppm): 0.95 (t, 3H, Ha, J = 7.3 Hz), 1.38–1.68 (m, 4H, Hb, Hc), 2.24 (s, 3H, Hd), 3.52 (d, 1H, He, J = 7.9  Hz), 4.03 (q, 1H, Hf, J = 5.8 Hz), 4.41 (dd, 1H, Hg, J = 6.1 Hz, 11.7 Hz), 4.52 (dd, 1H, Hh, J = 5.0 Hz, 11.7 Hz), 6.58 (d, 2H, Hi, J = 8.4 Hz), 7.01 (d, 2H, Hj, J = 8.0 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 13.8, 19.2, 20.4, 35.1, 52.4, 78.1, 113.8, 128.0, 130.1, 143.7. MS (ES ) m∕z = 229.07 [MH ], 199.24, 184.74, 118.00, 91.06.

4i (E)-N-(2-nitro-1-(p-tolyl)ethyl)-4-(phenyldiazenyl)aniline. Dark-red blubbery oil. IR (neat NaCl, cm−1): ν = 3397, 3064, 3035, 2956, 2924, 2860, 1605, 1558, 1516, 1460, 1434, 1411, 1377, 1339, 1313, 1278, 1240, 1186, 1142, 1100, 1075, 1024, 967, 919, 862, 834, 767, 722, 687, 668, 640, 548, 532. 1H NMR (CDCl3, 500 MHz) δ (ppm): 2.34 (s, 3H, Ha), 4.75 (d, Hb, 2H, J = 6.6 Hz), 4.84 (d, Hc, 1H, J = 6.7 Hz), 5.24 (m, Hd, 1H), 6.69 (d, 2H, He, J = 8.9 Hz), 7.20 (d, 2H, Hf, J = 7.9 Hz), 7.28 (d, 2H, Hg, J = 8.1 Hz), 7.39 (t, 1H, Hh, Jo = 7.3 Hz, Jm = 1.3 Hz), 7.46 (t, 2H, Hi, J = 7.9 Hz), 7.79 (d, 2H, Hj, Jo = 8.9 Hz, Jm = 2.0 Hz), 7.81 (d, 2H, Hk, J = 8.3 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 21.1, 56.1, 79.9, 113.5, 122.4, 125.1, 126.3, 129.0, 129.9, 130.1, 133.9, 138.8, 145.7, 148.3, 153.0. MS (ES ) m∕z = 361.18 [MH ], 197.18, 118.04, 91.90, 77.00, 64.97.

4j 1-(4-((1-(4-methoxyphenyl)-2-nitropropyl)amino)phenyl)ethanone. Yellow-red blubbery oil. IR (neat NaCl, cm−1): ν = 3348, 3059, 3004, 2962, 2939, 2906, 2839, 1656, 1602, 1556, 1514, 1458, 1439, 1426, 1388, 1365, 1307, 1281, 1254, 1184, 1147, 1122, 1083, 1034, 960, 876, 833, 759, 669, 636, 597, 532. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.56 (d, 3H, Ha, J = 6.8 Hz), 2.46 (s, 3H, Hb,), 3.79 (s, 3H, Hc,), 4.80 (t, 1H, Hd, J = 7.9 Hz), 4.99 (m, 1H, He), 5.05 (d, 1H, Hf, J = 6.8 Hz), 6.56 (d, 2H, Hg, J = 8.9 Hz), 6.89 (d, 2H, Hh, J = 8.8 Hz), 7.21 (d, 2H, Hi, J = 8.7 Hz), 7.74 (d, 2H, Hj, J = 8.8 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 14.1, 26.1, 55.3, 59.7, 86.3, 112.8, 114.6, 128.0, 130.5, 150.1, 159.8, 196.4. 1H NMR (CDCl3, 500 MHz) δ (ppm): 1.52 (d, Ha, 3H, J = 6.5 Hz), 2.45 (s, Hb, 3H), 3.78 (s, Hc, 3H), 4.85 (t, 1H, Hd, J = 7.8 Hz), 4.94 (m, 1H, He), 5.05 (d, 1H, Hf, J = 6.8 Hz), 6.54 (d, 2H, Hg, J = 8.9 Hz), 6.88 (d, 2H, Hh, J = 8.9 Hz), 7.23 (d, 2H, Hi, J = 8.6 Hz), 7.76 (d, 2H, Hj, J = 8.8 Hz). 13C NMR (CDCl3, 126 MHz) δ (ppm): 17.1, 26.0, 55.3, 60.3, 87.5, 112.7, 114.7, 128.0, 130.5, 150.1, 159.9, 196.4. MS (ES ) m∕z = 329.10 [MH ], 254.11, 148.03, 136.00, 117.01, 105.04.

4k 4-methyl-N-(2-nitro-1-(2-nitrophenyl)butyl)aniline. Red blubbery oil. IR (neat NaCl, cm−1): ν = 3397, 3054, 3025, 2978, 2936, 2920, 2876, 1621, 1593, 1555, 1523, 1488, 1456, 1405, 1377, 1332, 1329, 1300, 1269, 1256, 1186, 1173, 1142, 1110, 1075, 1014, 935, 884, 808, 760, 716, 633, 541. 1H NMR (CDCl3, 500 MHz) δ (ppm): 0.94 (t, 3H, Ha, J = 7.4 Hz), 1.66 (m, 1H, Hb), 2.08 (m, 1H, Hc), 2.2 (s, 3H, Hd), 4.46 (broad, 1H, He), 4.63 (m, 1H, Hf), 4.73 (m, 1H, Hg), 6.45 (d, 2H, Hh, J = 8.5 Hz), 6.90 (d, 2H, Hi, J = 8.7 Hz), 7.18 (m, 2H, Hj), 7.46 (m, 2H, Hk). 13C NMR (CDCl3, 126 MHz) δ (ppm): 10.4, 20.4, 24.8, 60.2, 94.6, 114.1, 122.4, 128.1, 128.6, 129.8, 132.3, 137.4, 143.2.1H NMR∗ (CDCl3, 500 MHz) δ (ppm): 0.97 (t, 3H, Ha, J = 7.3 Hz),1.90 (m, 1H, Hb), 2.14 (m, 1H, Hc), 4.24 (broad, 1H, Hd), 4.68 (m, 1H, He), 4.80 (m, 1H, Hf), 6.44 (d, 2H, Hg, J = 8.5 Hz), 6.92 (d, 2H, Hh, J = 9.1 Hz), 7.20 (m, 2H, Hi), 7.46 (m, 2H, Hj). 13C NMR (CDCl3, 126 MHz) δ (ppm): 10.7, 22.4, 24.8, 60.4, 93.7, 114.2, 122.4, 128.4, 128.6, 129.8, 132.2, 137.0, 143.4. MS (ES ) m/z = 314.12, 274.11, 210.04, 178.06, 131.10, 108.09, 93.04, 91.03, 60.81.

dd form - Mira.startflyjobs
dd form – Mira.startflyjobs | dd form 137 7 pdf

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